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Question from: Chemistry

\(\ce{MnO4^- (aq) + Y + 5Fe^2+ (aq) -> Mn^2+ (aq) + 5Fe^2+ (aq) + 4H2O (l)}\)

In the equation above, Y is:

A)  

\(5\mathrm{H^+}_{(aq)}\)

B)  

\(4\mathrm{H^+}_{(aq)}\)

C)  

\(10\mathrm{H^+}_{(aq)}\)

D)  

\(8\mathrm{H^+}_{(aq)}\)

Solutions

j

juanbacan

hace 18 días

Solution

0

Explanation (acidic medium redox balancing):

  • Note: On the products side the iron should be \(\ce{Fe^3+}\), not \(\ce{Fe^2+}\). The correct overall reaction in acid is: \[\ce{MnO4^- + Y + 5Fe^2+ -> Mn^2+ + 5Fe^3+ + 4H2O}\]
  • Half-reactions
    • \(\ce{MnO4^- -> Mn^2+}\): balance O with water and H with \(\ce{H+}\), then charge with electrons:
      \[\ce{MnO4^- + 8H+ + 5e- -> Mn^2+ + 4H2O}\]
    • \(\ce{Fe^2+ -> Fe^3+ + e-}\)
  • Combine: multiply the iron half-reaction by 5 to cancel 5 electrons and add: \[\ce{MnO4^- + 8H+ + 5Fe^2+ -> Mn^2+ + 5Fe^3+ + 4H2O}\]

Therefore, \(Y = \mathbf{\ce{8H+_{(aq)}}}\).

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