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Question from: Chemistry

6AgNO4(aq) + PH3(g) + 3H2O(l) → 6Ag(s) + H3PO3(g) + 6HNO3(aq) In the above reaction, the reducing agent is 

A)  

HNO3(aq)

B)  

H2O(l)

C)  

PH3(g)

D)  

AgNO3(aq)

Solutions

j

juanbacan

hace 2 meses

Solution

0

Correct Answer: PH₃(g)

Explanation:

  • In redox reactions, the reducing agent is the species that loses electrons (gets oxidized).
  • In the given reaction: \[ 6AgNO₃ + PH₃ + 3H₂O \;\;\rightarrow\;\; 6Ag + H₃PO₃ + 6HNO₃ \]
  • Silver (Ag⁺) ions from AgNO₃ are reduced to metallic silver (Ag). This means another species must be oxidized.
  • Phosphine, PH₃, is oxidized to phosphorous acid, H₃PO₃. - In PH₃, phosphorus has an oxidation state of –3. - In H₃PO₃, phosphorus has an oxidation state of +3. - So, phosphorus is oxidized from –3 to +3.
  • Therefore, PH₃ is the reducing agent because it donates electrons that reduce Ag⁺ to Ag.

Hence, the reducing agent is PH₃(g).

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