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Question from: Chemistry

If a reaction is exothermic and there is a great disorder, it means that

A)  

the reaction is static

B)  

the reaction is in a state of equilibrium

C)  

there will be a large increase in free energy

D)  

there will be a large decrease in free energy

Solutions

j

juanbacan

hace 2 meses

Solution

0

Correct answer: there will be a large decrease in free energy.

Explanation: For spontaneity, use Gibbs free energy: \( \Delta G = \Delta H - T\Delta S \).

  • Exothermic ⇒ \( \Delta H < 0 \)
  • Great disorder ⇒ \( \Delta S > 0 \)
  • Thus \( \Delta G = (\text{negative}) - T(\text{positive}) \) ⇒ more negative ⇒ large decrease in free energy.
  • Static / equilibrium — Not implied; equilibrium requires \( \Delta G = 0 \).
  • Large increase in free energy — Opposite of exothermic with increased entropy.

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