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Question from: Chemistry

2H2(g) + O2(g) ⇋ 2H2O(g) ΔH = - ve. What happens to the equilibrium constant of the reaction above if the temperature is increased?

A)  

it is unaffected

B)  

it becomes zero

C)  

it decrease

D)  

it increases

Solutions

j

juanbacan

hace 14 días

Solution

0

Correct answer: it decrease.

Explanation: The reaction is exothermic (ΔH < 0). By Le Châtelier/van ’t Hoff, increasing temperature favors the endothermic direction (the reverse here), so fewer products (H2O) are present at equilibrium. Therefore the equilibrium constant K (products/reactants) decreases as temperature increases.

  • It is unaffected — Only true if ΔH = 0.
  • It becomes zero — Impossible for a finite reversible system.
  • It increases — Would be true for an endothermic forward reaction (ΔH > 0), not here.

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