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Question from: Chemistry

In an endothermic reaction, if there is a loss in entropy the reaction will

A)  

Be indeterminate

B)  

Be spontaneous

C)  

Not be spontaneous

D)  

Be at equilibrium

Solutions

j

juanbacan

hace 12 días

Solution

0

Correct answer: Not be spontaneous

Explanation: Spontaneity is judged by Gibbs free energy: \( \Delta G = \Delta H - T\Delta S \). For an endothermic reaction, \( \Delta H > 0 \); a loss in entropy means \( \Delta S < 0 \). Then

\( \Delta G = (+) - T(-) = (+) + (+) \Rightarrow \Delta G > 0 \) at all temperatures, so the reaction is not spontaneous.

  • Be indeterminate — Incorrect. The signs make \( \Delta G \) definitely positive.
  • Be spontaneous — Incorrect. \( \Delta G \gt 0 \).
  • Not be spontaneousCorrect.
  • Be at equilibrium — Incorrect. Equilibrium requires \( \Delta G = 0 \), which cannot occur here for any positive temperature.

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